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Bifunctional Iminophosphorane Organocatalysts for Enantioselective Synthesis: Application to the Ketimine Nitro-Mannich Reaction

[Image: see text] The design, synthesis, and development of a new class of modular, strongly basic, and tunable bifunctional Brønsted base/H-bond-donor organocatalysts are reported. These catalysts incorporate a triaryliminophosphorane as the Brønsted basic moiety and are readily synthesized via a l...

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Main Authors: Núñez, Marta G., Farley, Alistair J. M., Dixon, Darren J.
פורמט: Artigo
שפה:Inglês
יצא לאור: American Chemical Society 2013
גישה מקוונת:https://ncbi.nlm.nih.gov/pmc/articles/PMC3931333/
https://ncbi.nlm.nih.gov/pubmed/24107070
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja409121s
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