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α-Arylation of Saturated Azacycles and N-Methylamines via Palladium(II)-catalyzed C(sp(3))–H Coupling

Pd(II)-catalyzed α-C(sp(3))–H arylation of pyrrolidines, piperidines, azepanes and N-methyl amines with arylboronic acids has been developed for the first time. This transformation is applicable to both a wide array of pyrrolidines and boronic acids, including heteroaromatic boronic acids. A diaster...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Spangler, Jillian E., Kobayashi, Yoshihisa, Verma, Pritha, Wang, Dong-Hui, Yu, Jin-Quan
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4822695/
https://ncbi.nlm.nih.gov/pubmed/26322957
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b06740
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