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Catalytic S(N)2′- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis
A catalytic method for site- and enantioselective addition of commercially available di-B(pin)-methane to allylic phosphates is introduced (pin = pinacolato). Transformations may be facilitated by an NHC-Cu complex (NHC = N-heterocyclic carbene) and products obtained in 63–95% yield, 88:12 to >98...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4813298/ https://ncbi.nlm.nih.gov/pubmed/26845488 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201600309 |
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