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Synthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinylaluminum Reagents

Catalytic enantioselective allylic substitution (EAS) reactions, which involve the use of alkyl- or aryl-substituted vinylaluminum reagents and afford 1,4-dienes containing a quaternary carbon stereogenic center at their C-3 site, are disclosed. The C–C bond forming transformations are promoted by 0...

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Bibliografiska uppgifter
Huvudupphovsmän: Gao, Fang, McGrath, Kevin P., Lee, Yunmi, Hoveyda, Amir H.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2010
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Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC2951504/
https://ncbi.nlm.nih.gov/pubmed/20860365
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja106829k
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