Chargement en cours...
Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC–Cu-Catalyzed Allylic Substitution
Catalytic enantioselective allylic substitutions that result in exclusive addition of an allenyl group (<2% propargyl addition) and formation of tertiary or quaternary C–C bonds are described. Commercially available allenylboronic acid pinacol ester is used (preparation of a more reactive but les...
Enregistré dans:
| Auteurs principaux: | , |
|---|---|
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2012
|
| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3267425/ https://ncbi.nlm.nih.gov/pubmed/22214185 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja211269w |
| Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|