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Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC–Cu-Catalyzed Substitution Reactions
[Image: see text] Allylic substitutions that afford α-substituted allylboronates bearing B-substituted tertiary or quaternary carbon stereogenic centers are presented. C–B bond forming reactions, catalyzed by chiral bidentate Cu–NHC complexes, are performed in the presence of commercially available...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2917266/ https://ncbi.nlm.nih.gov/pubmed/20681681 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja104254d |
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