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Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC–Cu-Catalyzed Substitution Reactions

[Image: see text] Allylic substitutions that afford α-substituted allylboronates bearing B-substituted tertiary or quaternary carbon stereogenic centers are presented. C–B bond forming reactions, catalyzed by chiral bidentate Cu–NHC complexes, are performed in the presence of commercially available...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Guzman-Martinez, Aikomari, Hoveyda, Amir H.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2010
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC2917266/
https://ncbi.nlm.nih.gov/pubmed/20681681
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja104254d
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