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NHC–Cu-Catalyzed Protoboration of Mono-Substituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism
[Image: see text] Two different types of NHC–Cu complexes catalyze protoborations of terminal allenes to afford valuable 1,1- or trisubstituted vinylboron species with high site- and stereoselectivity. The scope of the method, application to natural product synthesis and mechanistic basis for the ob...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3625862/ https://ncbi.nlm.nih.gov/pubmed/23461762 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol4004178 |
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