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NHC–Cu-Catalyzed Protoboration of Mono-Substituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism

[Image: see text] Two different types of NHC–Cu complexes catalyze protoborations of terminal allenes to afford valuable 1,1- or trisubstituted vinylboron species with high site- and stereoselectivity. The scope of the method, application to natural product synthesis and mechanistic basis for the ob...

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Bibliografiske detaljer
Main Authors: Meng, Fanke, Jung, Byunghyuck, Haeffner, Fredrik, Hoveyda, Amir H.
Format: Artigo
Sprog:Inglês
Udgivet: 2013
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3625862/
https://ncbi.nlm.nih.gov/pubmed/23461762
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol4004178
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