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Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron, 1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine–Cu Complex

[Image: see text] Catalytic enantioselective multicomponent processes involving bis(pinacolato)diboron [B(2)(pin)(2)], 1,3-enynes, and aldehydes are disclosed; the resulting compounds contain a primary C–B(pin) bond, as well as alkyne- and hydroxyl-substituted tertiary carbon stereogenic centers. A...

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מידע ביבליוגרפי
Main Authors: Meng, Fanke, Haeffner, Fredrik, Hoveyda, Amir H.
פורמט: Artigo
שפה:Inglês
יצא לאור: American Chemical Society 2014
גישה מקוונת:https://ncbi.nlm.nih.gov/pmc/articles/PMC4140502/
https://ncbi.nlm.nih.gov/pubmed/25089917
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5071202
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