Načítá se...
Catalytic S(N)2′- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis
A catalytic method for site- and enantioselective addition of commercially available di-B(pin)-methane to allylic phosphates is introduced (pin = pinacolato). Transformations may be facilitated by an NHC-Cu complex (NHC = N-heterocyclic carbene) and products obtained in 63–95% yield, 88:12 to >98...
Uloženo v:
| Vydáno v: | Angew Chem Int Ed Engl |
|---|---|
| Hlavní autoři: | , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2016
|
| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4813298/ https://ncbi.nlm.nih.gov/pubmed/26845488 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201600309 |
| Tagy: |
Přidat tag
Žádné tagy, Buďte první, kdo otaguje tento záznam!
|