Á lódáil...
Catalytic S(N)2′- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis
A catalytic method for site- and enantioselective addition of commercially available di-B(pin)-methane to allylic phosphates is introduced (pin = pinacolato). Transformations may be facilitated by an NHC-Cu complex (NHC = N-heterocyclic carbene) and products obtained in 63–95% yield, 88:12 to >98...
Na minha lista:
| Foilsithe in: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , |
| Formáid: | Artigo |
| Teanga: | Inglês |
| Foilsithe: |
2016
|
| Ábhair: | |
| Rochtain Ar Líne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4813298/ https://ncbi.nlm.nih.gov/pubmed/26845488 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201600309 |
| Clibeanna: |
Cuir Clib Leis
Gan Chlibeanna, Bí ar an gcéad duine leis an taifead seo a chlibeáil!
|