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Synthesis and Dynamics of Nanosized Phenylene–Ethynylene–Butadiynylene Rotaxanes and the Role of Shape Persistence

Phenylacetylene‐based [2]rotaxanes were synthesized by a covalent‐template approach by aminolysis of the corresponding prerotaxanes. The wheel and the bulky stoppers are made of phenylene–ethynylene–butadiynylene macrocycles of the same size. The stoppers are large enough to enable the synthesis and...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Schweez, Christopher, Shushkov, Philip, Grimme, Stefan, Höger, Sigurd
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4797704/
https://ncbi.nlm.nih.gov/pubmed/26836984
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201509702
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