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Synthesis and Dynamics of Nanosized Phenylene–Ethynylene–Butadiynylene Rotaxanes and the Role of Shape Persistence

Phenylacetylene‐based [2]rotaxanes were synthesized by a covalent‐template approach by aminolysis of the corresponding prerotaxanes. The wheel and the bulky stoppers are made of phenylene–ethynylene–butadiynylene macrocycles of the same size. The stoppers are large enough to enable the synthesis and...

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Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: Schweez, Christopher, Shushkov, Philip, Grimme, Stefan, Höger, Sigurd
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2016
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4797704/
https://ncbi.nlm.nih.gov/pubmed/26836984
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201509702
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