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Synthesis and Dynamics of Nanosized Phenylene–Ethynylene–Butadiynylene Rotaxanes and the Role of Shape Persistence

Phenylacetylene‐based [2]rotaxanes were synthesized by a covalent‐template approach by aminolysis of the corresponding prerotaxanes. The wheel and the bulky stoppers are made of phenylene–ethynylene–butadiynylene macrocycles of the same size. The stoppers are large enough to enable the synthesis and...

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發表在:Angew Chem Int Ed Engl
Main Authors: Schweez, Christopher, Shushkov, Philip, Grimme, Stefan, Höger, Sigurd
格式: Artigo
語言:Inglês
出版: John Wiley and Sons Inc. 2016
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC4797704/
https://ncbi.nlm.nih.gov/pubmed/26836984
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201509702
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