Copper‐Catalyzed Borylation of Cyclic Sulfamidates: Access to Enantiomerically Pure (β‐and γ‐Amino­alkyl)boronic Esters

Cyclic sulfamidates undergo borylation under copper‐catalyzed conditions using B(2)pin(2) to give enantiomerically (and diasteromerically) defined (aminoalkyl)boronic esters. External iodide is essential, but the intermediacy of simple alkyl iodides has been excluded; N‐sulfated intermediates are ke...

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Detalles Bibliográficos
Publicado en:European J Org Chem
Main Authors: Ursinyova, Nina, Bedford, Robin B., Gallagher, Timothy
Formato: Artigo
Idioma:Inglês
Publicado: WILEY‐VCH Verlag 2015
Assuntos:
Communications
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4770434/
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201501492
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