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Copper-Catalyzed Borylative Aromatization of p-Quinone Methides: Enantioselective Synthesis of Dibenzylic Boronates
[Image: see text] In this report, we establish that DM-Segphos copper(I) complexes are efficient catalysts for the enantioselective borylation of para-quinone methides. This method provides straightforward access to chiral monobenzylic and dibenzylic boronic esters, with enantiomeric ratios up to 96...
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| Vydáno v: | ACS Catal |
|---|---|
| Hlavní autoři: | , , , , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
American Chemical
Society
2015
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| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4831668/ https://ncbi.nlm.nih.gov/pubmed/27088045 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.5b02742 |
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