Copper-Catalyzed Borylative Aromatization of p-Quinone Methides: Enantioselective Synthesis of Dibenzylic Boronates

[Image: see text] In this report, we establish that DM-Segphos copper(I) complexes are efficient catalysts for the enantioselective borylation of para-quinone methides. This method provides straightforward access to chiral monobenzylic and dibenzylic boronic esters, with enantiomeric ratios up to 96...

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Bibliografski detalji
Izdano u:ACS Catal
Glavni autori: Jarava-Barrera, Carlos, Parra, Alejandro, López, Aurora, Cruz-Acosta, Fabio, Collado-Sanz, Daniel, Cárdenas, Diego J., Tortosa, Mariola
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2015
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4831668/
https://ncbi.nlm.nih.gov/pubmed/27088045
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.5b02742
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