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A Single Enzyme Transforms a Carboxylic Acid to a Nitrile through an Amide Intermediate
The biosynthesis of nitriles is known to occur in specialized pathways involving multiple enzymes; however, in bacterial and archeal biosyntheses of 7-deazpurines, a single enzyme, ToyM, catalyzes the conversion of the carboxylic acid containing 7-carboxy-7-deazaguanine (CDG) to its corresponding ni...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4767005/ https://ncbi.nlm.nih.gov/pubmed/26228534 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201504505 |
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