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Preparation of Enantiomerically Pure Perfluorobutanesulfinamide and Its Application to the Asymmetric Synthesis of α-Amino Acids
A high yielding and practical two-step synthesis of enantiomerically pure perfluorobutanesulfinamide from Senanayake’s 2-aminoindanol-derived sulfinyl transfer reagent was developed and carried out on multi-gram scale. Straightforward condensation of this sulfinamide with ethyl glyoxylate provided t...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4761297/ https://ncbi.nlm.nih.gov/pubmed/26844947 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.5b02700 |
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