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Hydride Transfer in DHFR by Transition Path Sampling, Kinetic Isotope Effects, and Heavy Enzyme Studies

Escherichia coli dihydrofolate reductase (ecDHFR) is used to study fundamental principles of enzyme catalysis. It remains controversial whether fast protein motions are coupled to the hydride transfer catalyzed by ecDHFR. Previous studies with heavy ecDHFR proteins labeled with (13)C, (15)N, and non...

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Bibliografiset tiedot
Julkaisussa:Biochemistry
Päätekijät: Wang, Zhen, Antoniou, Dimitri, Schwartz, Steven D., Schramm, Vern L.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2015
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC4752833/
https://ncbi.nlm.nih.gov/pubmed/26652185
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.5b01241
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