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Nucleophilic arylation with tetraarylphosphonium salts

Organic phosphonium salts have served as important intermediates in synthetic chemistry. But the use of a substituent on the positive phosphorus as a nucleophile to construct C–C bond remains a significant challenge. Here we report an efficient transition-metal-free protocol for the direct nucleophi...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Deng, Zuyong, Lin, Jin-Hong, Xiao, Ji-Chang
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4740112/
https://ncbi.nlm.nih.gov/pubmed/26822205
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms10337
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