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Total Synthesis of (−)-Enigmazole A

[Image: see text] A highly convergent, stereocontrolled total synthesis of the architecturally complex marine sponge metabolite (−)-enigmazole A has been achieved. Highlights include an unprecedented late-stage large-fragment Petasis–Ferrier union/rearrangement, a multicomponent Type I Anion Relay C...

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Publicat a:J Am Chem Soc
Autors principals: Ai, Yanran, Kozytska, Mariya V., Zou, Yike, Khartulyari, Anton S., Smith, Amos B.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2015
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4700938/
https://ncbi.nlm.nih.gov/pubmed/26632969
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b11540
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