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Presolvated Electron Reactions with Methyl Acetoacetate: Electron Localization, Proton-Deuteron Exchange, and H-Atom Abstraction
Radiation-produced electrons initiate various reaction processes that are important to radiation damage to biomolecules. In this work, the site of attachment of the prehydrated electrons with methyl acetoacetate (MAA, CH(3)-CO-CH(2)-COOCH(3)) at 77 K and subsequent reactions of the anion radical (CH...
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| Опубликовано в: : | Molecules |
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| Главные авторы: | , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
MDPI
2014
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4678098/ https://ncbi.nlm.nih.gov/pubmed/25255751 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules190913486 |
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