Mechanisms for Hydrogen-Atom Abstraction by Mononuclear Copper(III) Cores: Hydrogen-Atom Transfer or Concerted Proton-Coupled Electron Transfer?

In a possibly biomimetic fashion, formally copper(III)−oxygen complexes LCu(III)−OH (1) and LCu(III)−OOCm (2) (L(2−) = N,N′-bis(2,6diisopropylphenyl)-2,6-pyridinedicarboxamide, Cm = α,α-dimethylbenzyl) have been shown to activate X−H bonds (X = C, O). Herein, we demonstrate similar X−H bond activati...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Mandal, Mukunda, Elwell, Courtney E., Bouchey, Caitlin J., Zerk, Timothy J., Tolman, William B., Cramer, Christopher J.
Format: Artigo
Language:Inglês
Published: 2019
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7197025/
https://ncbi.nlm.nih.gov/pubmed/31617707
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b08109
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