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Presolvated Electron Reactions with Methyl Acetoacetate: Electron Localization, Proton-Deuteron Exchange, and H-Atom Abstraction

Radiation-produced electrons initiate various reaction processes that are important to radiation damage to biomolecules. In this work, the site of attachment of the prehydrated electrons with methyl acetoacetate (MAA, CH(3)-CO-CH(2)-COOCH(3)) at 77 K and subsequent reactions of the anion radical (CH...

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Pubblicato in:Molecules
Autori principali: Petrovici, Alex, Adhikary, Amitava, Kumar, Anil, Sevilla, Michael D.
Natura: Artigo
Lingua:Inglês
Pubblicazione: MDPI 2014
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4678098/
https://ncbi.nlm.nih.gov/pubmed/25255751
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules190913486
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