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Presolvated Low Energy Electron Attachment to Peptide Methyl esters in Aqueous Solution: C-O Bond Cleavage at 77K

In this study, the reactions of presolvated electrons with glycine methyl ester and N-acetylalanylalanine methyl ester (N-aAAMe) are investigated by electron spin resonance (ESR) spectroscopy and DFT calculations. Electrons were produced by gamma irradiation in neutral 7.5 M LiCl-D(2)O aqueous glass...

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Detalhes bibliográficos
Main Authors: Kheir, Jeanette, Chomicz, Lidia, Engle, Alyson, Rak, Janusz, Sevilla, Michael D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3617489/
https://ncbi.nlm.nih.gov/pubmed/23406302
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp400176c
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