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Prototropic Equilibria in DNA Containing One-electron Oxidized GC: Intra-duplex vs. Duplex to Solvent Deprotonation
By use of ESR and UV-vis spectral studies, this work identifies the protonation states of one-electron oxidized G:C (viz. G•(+):C, G(N1-H)•:C(+H(+)), G(N1-H)•:C, and G(N2-H)•:C) in a DNA oligomer d[TGCGCGCA](2.) Benchmark ESR and UV-vis spectra from one electron oxidized 1-Me-dGuo are employed to an...
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| Publicado no: | Phys Chem Chem Phys |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4677782/ https://ncbi.nlm.nih.gov/pubmed/21491657 |
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