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Photo-excitation of adenine cation radical [A•(+)] in the near UV-vis region produces sugar radicals in Adenosine and in its nucleotides

In this study, we report the formation of ribose sugar radicals in high yields (85 – 100%) via photo-excitation of adenine cation radical (A•(+)) in Ado and its ribonucleotides. Photo-excitation of A•(+) at low temperatures in homogenous aqueous glassy samples of Ado, 2′-AMP, 3′-AMP and 5′-AMP forms...

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Main Authors: Adhikary, Amitava, Khanduri, Deepti, Kumar, Anil, Sevilla, Michael D.
格式: Artigo
語言:Inglês
出版: 2008
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC3290692/
https://ncbi.nlm.nih.gov/pubmed/19367991
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp808139e
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