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The Guanine Cation Radical: Investigation of Deprotonation States by ESR and DFT
This work reports ESR studies that identify the favored site of deprotonation of the guanine cation radical (G•(+)) in an aqueous medium at 77 K. Using ESR and UV-visible spectroscopy, one-electron oxidized guanine is investigated in frozen aqueous D(2)O solutions of 2′-deoxyguanosine (dGuo) at low...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2526163/ https://ncbi.nlm.nih.gov/pubmed/17125389 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp064361y |
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