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An ESR and DFT study of Hydration of the 2′-Deoxyuridine-5-yl Radical: Possible Hydroxyl Radical Intermediate
The mechanism of radiation-induced frank strand break formation in irradiated 5-bromo-2′-deoxyuridine (BrdU)-labelled DNA is still unclear, despite the proven radiosensitizing property of BrdU. Combination of ESR spectroscopy and quantum chemical modelling points to a simple reaction between the uri...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4213299/ https://ncbi.nlm.nih.gov/pubmed/25306924 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4cc07089e |
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