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Single Turnover Reveals Oxygenated Intermediates in Toluene/o-Xylene Monooxygenase in the Presence of the Native Redox Partners
Toluene/o-xylene monooxygenase (ToMO) is a non-heme diiron protein that activates O(2) for subsequent arene oxidation. ToMO utilizes four protein components, a catalytic hydroxylase (ToMOH), a regulatory protein (To-MOD), a Rieske protein (ToMOC), and a reductase (ToMOF). Here, we examine O(2) activ...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4666740/ https://ncbi.nlm.nih.gov/pubmed/26267757 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b07055 |
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