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Single Turnover Reveals Oxygenated Intermediates in Toluene/o-Xylene Monooxygenase in the Presence of the Native Redox Partners
Toluene/o-xylene monooxygenase (ToMO) is a non-heme diiron protein that activates O(2) for subsequent arene oxidation. ToMO utilizes four protein components, a catalytic hydroxylase (ToMOH), a regulatory protein (To-MOD), a Rieske protein (ToMOC), and a reductase (ToMOF). Here, we examine O(2) activ...
Gorde:
| Argitaratua izan da: | J Am Chem Soc |
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| Egile Nagusiak: | , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2015
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4666740/ https://ncbi.nlm.nih.gov/pubmed/26267757 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b07055 |
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