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Catalytic Alkene Carboaminations Enabled by Oxidative Proton-Coupled Electron Transfer
Here we describe a dual catalyst system comprised of an iridium photocatalyst and weak phosphate base that is capable of both selectively homolyzing the N–H bonds of N-arylamides (bond dissociation free energies ~ 100 kcal/mol) via concerted proton-coupled electron transfer (PCET) and mediating effi...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2015
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4643263/ https://ncbi.nlm.nih.gov/pubmed/26166022 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05377 |
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