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Fragment Couplings via CO(2) Extrusion–Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox
In this study we demonstrate that molecular fragments, which can be readily coupled via a simple, in situ RO—C=OR bond-forming reaction, can subsequently undergo metal insertion–decarboxylation–recombination to generate C(sp)(2)–C(sp)(3) bonds when subjected to metallaphotoredox catalysis. In this e...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4632494/ https://ncbi.nlm.nih.gov/pubmed/26333771 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b08304 |
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