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Fragment Couplings via CO(2) Extrusion–Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox

In this study we demonstrate that molecular fragments, which can be readily coupled via a simple, in situ RO—C=OR bond-forming reaction, can subsequently undergo metal insertion–decarboxylation–recombination to generate C(sp)(2)–C(sp)(3) bonds when subjected to metallaphotoredox catalysis. In this e...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Le, Chi “Chip”, MacMillan, David W. C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4632494/
https://ncbi.nlm.nih.gov/pubmed/26333771
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b08304
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