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O–H hydrogen bonding promotes H-atom transfer from a C–H bonds for C-alkylation of alcohols

The efficiency and selectivity of hydrogen atom transfer from organic molecules are often difficult to control in the presence of multiple potential hydrogen atom donors and acceptors. Here, we describe the mechanistic evaluation of a mode of catalytic activation that accomplishes the highly selecti...

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Bibliografiske detaljer
Udgivet i:Science
Main Authors: Jeffrey, Jenna L., Terrett, Jack A., MacMillan, David W. C.
Format: Artigo
Sprog:Inglês
Udgivet: 2015
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4632491/
https://ncbi.nlm.nih.gov/pubmed/26316601
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aac8555
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