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O–H hydrogen bonding promotes H-atom transfer from a C–H bonds for C-alkylation of alcohols

The efficiency and selectivity of hydrogen atom transfer from organic molecules are often difficult to control in the presence of multiple potential hydrogen atom donors and acceptors. Here, we describe the mechanistic evaluation of a mode of catalytic activation that accomplishes the highly selecti...

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Detaylı Bibliyografya
Yayımlandı:Science
Asıl Yazarlar: Jeffrey, Jenna L., Terrett, Jack A., MacMillan, David W. C.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2015
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC4632491/
https://ncbi.nlm.nih.gov/pubmed/26316601
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aac8555
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