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O–H hydrogen bonding promotes H-atom transfer from a C–H bonds for C-alkylation of alcohols

The efficiency and selectivity of hydrogen atom transfer from organic molecules are often difficult to control in the presence of multiple potential hydrogen atom donors and acceptors. Here, we describe the mechanistic evaluation of a mode of catalytic activation that accomplishes the highly selecti...

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Detalhes bibliográficos
Publicado no:Science
Main Authors: Jeffrey, Jenna L., Terrett, Jack A., MacMillan, David W. C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4632491/
https://ncbi.nlm.nih.gov/pubmed/26316601
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aac8555
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