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C–H Alkylation via Multisite-Proton-Coupled Electron Transfer of an Aliphatic C–H Bond
The direct, site-selective alkylation of unactivated C(sp(3))–H bonds in organic substrates is a long-standing goal in synthetic chemistry. General approaches to the activation of strong C–H bonds include radical-mediated processes involving highly reactive intermediates, such as heteroatom-centered...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6856561/ https://ncbi.nlm.nih.gov/pubmed/31356059 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b06834 |
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