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Higher-Order Cyclopropenimine Superbases. Direct Neutral Brønsted Base Catalyzed: Michael Reactions with α-Aryl Esters
The synthesis and characterization of six new classes of higher-order superbases, including five that incorporate cyclopropenimine functionality, has been achieved. We propose a nomenclature that designates these as the CG(2), GC(2), PC(3), PC(1), C(3), and GP(2) classes of superbases. The pK(BH+) v...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4617652/ https://ncbi.nlm.nih.gov/pubmed/26131761 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05033 |
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