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Catalytic Kinetic Resolution of Disubstituted Piperidines by Enantioselective Acylation: Synthetic Utility and Mechanistic Insights

The catalytic kinetic resolution of cyclic amines with achiral N-heterocyclic carbenes (NHC) and chiral hydroxamic acids has emerged as a promising method to obtain enantioenriched amines with high selectivity factors. In this report, we describe the catalytic kinetic resolution of disubstituted pip...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Wanner, Benedikt, Kreituss, Imants, Gutierrez, Osvaldo, Kozlowski, Marisa C., Bode, Jeffrey W.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4601563/
https://ncbi.nlm.nih.gov/pubmed/26308097
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b07201
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