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Effect of Base Stacking on the Acid-Base Properties of the Adenine Cation Radical [A•(+)] in Solution: ESR and DFT Studies
In this study, the acid–base properties of the adenine cation radical are investigated by means of experiment and theory. Adenine cation radical (A•(+)) is produced by one-electron oxidation of dAdo and of the stacked DNA-oligomer (dA)(6) by Cl(2)•(−) in aqueous glass (7.5 M LiCl in H(2)O and in D(2...
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| Gepubliceerd in: | J Am Chem Soc |
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| Hoofdauteurs: | , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2008
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4590776/ https://ncbi.nlm.nih.gov/pubmed/18611019 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja802122s |
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