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Protonation state of the Cu(4)S(2) Cu(Z) site in nitrous oxide reductase: redox dependence and insight into reactivity

Spectroscopic and computational methods have been used to determine the protonation state of the edge sulfur ligand in the Cu(4)S(2) Cu(Z) form of the active site of nitrous oxide reductase (N(2)OR) in its 3Cu(I)Cu(II) (1-hole) and 2Cu(I)2Cu(II) (2-hole) redox states. The EPR, absorption, and MCD sp...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Veröffentlicht in:Chem Sci
Hauptverfasser: Johnston, Esther M., Dell'Acqua, Simone, Pauleta, Sofia R., Moura, Isabel, Solomon, Edward I.
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2015
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4583207/
https://ncbi.nlm.nih.gov/pubmed/26417423
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02102b
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