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Protonation state of the Cu(4)S(2) Cu(Z) site in nitrous oxide reductase: redox dependence and insight into reactivity
Spectroscopic and computational methods have been used to determine the protonation state of the edge sulfur ligand in the Cu(4)S(2) Cu(Z) form of the active site of nitrous oxide reductase (N(2)OR) in its 3Cu(I)Cu(II) (1-hole) and 2Cu(I)2Cu(II) (2-hole) redox states. The EPR, absorption, and MCD sp...
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| Izdano u: | Chem Sci |
|---|---|
| Glavni autori: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Royal Society of Chemistry
2015
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4583207/ https://ncbi.nlm.nih.gov/pubmed/26417423 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02102b |
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