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Two-electron Reduction versus One-electron Oxidation of the Type 3 Pair in the Multicopper Oxidases
Multicopper Oxidases (MCOs) utilize an electron shuttling Type 1 Cu (T1) site in conjunction with a mononuclear Type 2 (T2) and a binuclear Type 3 (T3) site, arranged in a trinuclear copper cluster (TNC), to reduce O(2) to H(2)O. Reduction of O(2) occurs with limited overpotential indicating that al...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4504817/ https://ncbi.nlm.nih.gov/pubmed/26075678 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b04136 |
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