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Molecular Origin of Rapid vs. Slow Intramolecular Electron Transfer in the Catalytic Cycle of the Multicopper Oxidases

Kinetic measurements on single-turnover processes in Laccase establish fast Type 1 (T1) Cu to tri-nuclear Cu cluster (TNC) intramolecular electron transfer (IET) in the reduction of the native intermediate (NI), the fully oxidized form of the enzyme formed immediately after O-O bond cleavage in the...

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Detaylı Bibliyografya
Asıl Yazarlar: Heppner, David E., Kjaergaard, Christian H., Solomon, Edward I.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2013
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC3807568/
https://ncbi.nlm.nih.gov/pubmed/23902255
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4064525
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