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Mechanism of the Reduction of the Native Intermediate in the Multicopper Oxidases: Insights into Rapid Intramolecular Electron Transfer in Turnover
[Image: see text] The multicopper oxidases (MCOs) are the family of enzymes that catalyze the 4-electron reduction of O(2) to H(2)O coupled to the four 1-electron oxidations of substrate. In the catalytic cycle electrons are transferred intramolecularly over ∼13 Å from a Type 1 (T1) Cu site that acc...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4291763/ https://ncbi.nlm.nih.gov/pubmed/25490729 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja509150j |
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