Direct Evidence for a Peroxide Intermediate and a Reactive Enzyme–Substrate–Dioxygen Configuration in a Cofactor-free Oxidase**

Cofactor-free oxidases and oxygenases promote and control the reactivity of O(2) with limited chemical tools at their disposal. Their mechanism of action is not completely understood and structural information is not available for any of the reaction intermediates. Near-atomic resolution crystallogr...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Bui, Soi, von Stetten, David, Jambrina, Pablo G, Prangé, Thierry, Colloc'h, Nathalie, de Sanctis, Daniele, Royant, Antoine, Rosta, Edina, Steiner, Roberto A
Format: Artigo
Idioma:Inglês
Publicat: WILEY-VCH Verlag 2014
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4502973/
https://ncbi.nlm.nih.gov/pubmed/25314114
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201405485
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