Direct Evidence for a Peroxide Intermediate and a Reactive Enzyme–Substrate–Dioxygen Configuration in a Cofactor-free Oxidase**

Cofactor-free oxidases and oxygenases promote and control the reactivity of O(2) with limited chemical tools at their disposal. Their mechanism of action is not completely understood and structural information is not available for any of the reaction intermediates. Near-atomic resolution crystallogr...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Bui, Soi, von Stetten, David, Jambrina, Pablo G, Prangé, Thierry, Colloc'h, Nathalie, de Sanctis, Daniele, Royant, Antoine, Rosta, Edina, Steiner, Roberto A
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2014
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4502973/
https://ncbi.nlm.nih.gov/pubmed/25314114
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201405485
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