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Reversed-Polarity Synthesis of Diaryl Ketones through Palladium-Catalyzed Direct Arylation of 2-Aryl-1,3-dithianes

An umpolung approach to the synthesis of diaryl ketones has been developed based on in situ generation of acyl anion equivalents and their catalytic arylation. This method entails the base promoted palladium catalyzed direct C–H arylation of 2 The resulting 2,2-diaryl-1,3-dithianes with aryl bromide...

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Detalhes bibliográficos
Publicado no:Adv Synth Catal
Main Authors: Yucel, Baris, Walsh, Patrick J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4500739/
https://ncbi.nlm.nih.gov/pubmed/26185491
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201400695
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