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Reversed-Polarity Synthesis of Diaryl Ketones through Palladium-Catalyzed Direct Arylation of 2-Aryl-1,3-dithianes

An umpolung approach to the synthesis of diaryl ketones has been developed based on in situ generation of acyl anion equivalents and their catalytic arylation. This method entails the base promoted palladium catalyzed direct C–H arylation of 2 The resulting 2,2-diaryl-1,3-dithianes with aryl bromide...

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Vydáno v:Adv Synth Catal
Hlavní autoři: Yucel, Baris, Walsh, Patrick J.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2014
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4500739/
https://ncbi.nlm.nih.gov/pubmed/26185491
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201400695
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