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The Isomerization of Allylrhodium Intermediates in the Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines**

Allylrhodium species generated from potassium allyltrifluoroborates can undergo isomerization by 1,4-rhodium(I) migration to give more complex isomers, which then react with cyclic imines to provide products with up to three new stereochemical elements. High enantioselectivities are obtained using c...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Hepburn, Hamish B, Lam, Hon Wai
Format: Artigo
Sprog:Inglês
Udgivet: WILEY-VCH Verlag 2014
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4497600/
https://ncbi.nlm.nih.gov/pubmed/25205604
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201407233
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