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The Isomerization of Allylrhodium Intermediates in the Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines**
Allylrhodium species generated from potassium allyltrifluoroborates can undergo isomerization by 1,4-rhodium(I) migration to give more complex isomers, which then react with cyclic imines to provide products with up to three new stereochemical elements. High enantioselectivities are obtained using c...
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| Опубликовано в: : | Angew Chem Int Ed Engl |
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| Главные авторы: | , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
WILEY-VCH Verlag
2014
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4497600/ https://ncbi.nlm.nih.gov/pubmed/25205604 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201407233 |
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